What are PFAS?
PFAS are per- and polyfluoroalkyl substances. PFAS is a class of chemicals found in various industrial and consumer goods. For instance, you may find them in food packaging, textiles, cosmetics, and frequently in aqueous film-forming foams (AFFFs) used to extinguish fires. PFAS chemicals are known for repelling grease, water, and stains, making them widely used in various applications. These chemicals are stable and persistent, earning them the nickname “forever chemicals” because they do not readily biodegrade, or break down easily in the environment.
Numerous researchers suggested PFAS are abundant in aquatic systems and toxic to a range of aquatic organisms, with additional concerns of bioaccumulation of PFAS. PFAS accumulate in sediments and aquatic organisms, which pose health risks to wildlife and humans through the food chain. Research suggests linkages of PFAS to disruption of endocrine function, reproduction, and development in aquatic organisms. Research suggests similar linkages of PFAS to humans, like increased cancer risk, immune system suppression, endocrine and reproductive disruption, and child developmental concerns.
The United States Geological Survey (USGS) estimated that at least 45% of the United States’ tap water has one or more PFAS chemicals (Smalling et al. 2023). At least one PFAS was identified in 60% of public wells and 20% of domestic wells supplying drinking water in the eastern United States (McMahon et al. 2022).
Have PFAS been found in Walton County drinking water and surface waters?
Measured PFAS in Florida and Walton County Drinking Waters
Figure 1. Map with measured total PFAS in drinking water samples across a gradient of low concentrations (green dots) to medium concentrations (yellow dots) to higher concentrations (red dots). Shaded map colors are the predicted total PFAS using estimated values of PFAS concentrations from low (green) to high (red). Data, figure, and result interpolation from Sinkway et al. 2024.
A team of researchers completed a comprehensive statewide assessment of PFAS in Florida drinking water (Sinkway et al. 2024). The team collected 448 drinking water samples across all 67 Florida counties. The drinking water samples were analyzed for 31 PFAS, where 19 PFAS were found in at least one drinking water sample. The top five most frequently detected PFAS across Florida were 6:2 fluorotelomer sulfonate (6:2 FTS) (in 84% of the samples analyzed), Perfluorooctanoic acid (PFOA) (65%), linear perfluorooctane sulfonate (PFOS) (65%), branched PFOS (64%), and perfluorobutane sulfonic acid (PFBS).
A total of 107 taps had PFOA or PFOS concentrations above 4 ng/L (ppt), where the maximum total PFAS concentration in a tap was 219 ng/L. A maximum contaminant level for PFOA and PFOS of 4 ng/L was implemented by the United States Environmental Protection Agency National Primary Drinking Water Regulation as of May 14, 2025 (USEPA, 2025). Overall, 8% of the drinking water samples analyzed exceeded 4 ng/L for PFOA and 16% for PFOS. The average total PFAS in city water was 15.6 ng/L, and in well water was 4.5 ng/L across Florida.
Walton County was not ranked in the 12 Florida counties with the highest maximum and average total PFAS concentrations (ng/L) in drinking water (Table 1). Walton County was not included in the rankings of Florida counties with the lowest maximum and average total PFAS concentrations (ng/L) in drinking water as the total number of samples (n=3) was below the required 5 total number sample requirement (Table 1). Among the three drinking water samples collected, the maximum PFAS concentration measured was 0 ng/L with an average of 0 ng/L. Walton County had no drinking water samples exceeding the 4 ng/L standard for PFOA.
Table 1. The 12 Florida counties with highest and lowest total PFAS drinking water concentrations (ng/L). Data, figure, and result interpolation from Sinkway et al. 2024.
Measured PFAS in Florida and Walton County Surface Waters
A team of researchers completed a comprehensive statewide assessment of PFAS in Florida surface waters (Camacho et al. 2024). A network of citizen scientists collected 2,323 surface water samples across the 67 Florida counties. These surface water samples were analyzed for 50 PFAS, with 33 PFAS being detected in at least one surface water sample across Florida. The top five most frequently detected PFAS were perfluorooctanoic acid (PFOA) (94% of the samples), perfluorobutane sulfonic acid (PFBS) (65%), perfluorohexanoic acid (PFHxA) (61%), perfluorononanoic acid (PFNA) (54%), and perfluorooctane sulfonate (PFOS) (53%).
There were 915 surface water samples (39%) with PFOA concentrations above 4 ng/L and 920 samples (40%) with PFOS above 4 ng/L. All counties had at least one sample with PFOA, 96% had PFNA, 93% had PFBS, 91% had PFOS, and 82% of counties had PFHxA. The average PFAS detected among counties ranged from 2 ng/L of PFNA to 10 ng/L of PFOS. The maximum PFAS detected among counties ranged from 81 ng/L of PFOA to 1135 ng/L of PFOS.
Figure 2. Surface water sampled sites with detected PFAS, where the dots’ color represents the total PFAS concentration measured. Map B shows predicted PFAS levels based on measured total PFAS concentrations in surface water samples. Note that these values do not represent predicted PFAS concentrations on land. Data, figure, and result interpolation from Camacho et al. 2024.
A total of 18 surface water samples were collected in Walton County (Figure 2). Walton County ranked 51st among Florida counties with one surface water sample (one sample out of 18 total or 5%) with PFOA above 4 ng/L. Walton County ranked 42nd for the number of samples with two samples (11%) above 4 ng/L for PFOS. The average total PFAS concentration detected in a surface water sample was 6 ng/L, while the maximum total PFAS concentration detected in a sample was 29 ng/L.
Dr. Bowden, with the University of Florida’s College of Veterinary Medicine and Chemistry Department, led the PFAS research shared here. Dr. Bowden has extensive information on the Bowden Lab website (https://www.bowdenlaboratory.com/dr-bowden.html), including an interactive map of all the PFAS surface water samples collected in Florida. Select Okaloosa County under the filter section to see the surface water samples and learn more about the PFAS information for each sample collected in Okaloosa County (https://www.bowdenlaboratory.com/florida-surface-water.html).
What does this mean for Walton County?
PFAS were not detected in drinking waters in Walton County. However, the sample size, or the number of samples, was small with three total samples collected and analyzed. PFAS were detected in surface waters in Walton County. Although not the highest concentrations or most frequent identified in Florida, there were surface water samples above USEPA’s 4 ng/L contaminant level standard for PFOA and PFOS.
Understanding what PFAS are and joining in educational conversations about PFAS helps the Walton County community. Efforts that support continued sampling and extended monitoring also increase our understanding of PFAS concentrations in Walton County’s drinking and surface waters. If you want to learn more about PFAS or join community scientists’ efforts to expand PFAS water monitoring, please contact Dana Stephens, Florida Sea Grant Extension Agent with the UF/IFAS Okaloosa County Extension Office.
References
Camacho, C.G., et al. 2024. Statewide surveillance and mapping of PFAS in Florida surface waters. American Chemical Society, 4: 434-4355. https://doi.org/10.1021/acsestwater
United States Environmental Protection Agency (USEPA). 2025. Per- and polyfluoroalkyl substances (PFAS) final PFAS national primary drinking water regulation. https://www.epa.gov/sdwa/and-polyfluoroalkyl-substances-pfas
McMahon, P.B., Tokranov, A.K., and Bexfield, L.M. 2022. Perfluoroalkyl and polyfluoroalkyl substances in groundwater used as a source of drinking water in the Eastern United States. Environmental Science and Technology 56(4): 2279-2288. https://doi.org/10.1021/acs.est.1c04795
Skinkway, T.D., et al. 2024. Crowdsourcing citizens for statewide mapping of per- and polyfluoroalkyl substances (PFAS) in Florida drinking water. Science of the Total Environment, 926: 1-9. https://doi.org/10.1016/j.scitotenv.2024.171932
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